Thermoset Composites - Preparation, Properties and Applications

von: Khan, A.

Materials Research Forum LLC, 2018

ISBN: 9781945291876 , 350 Seiten

Format: PDF

Kopierschutz: Wasserzeichen

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Preis: 110,00 EUR

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Thermoset Composites - Preparation, Properties and Applications


 

front-matter

2

Thermoset Composites: Preparation, Properties and Applications

2

Table of Contents

4

Preface

6

Energy Absorption of Natural Fibre Reinforced Thermoset Polymer Composites Materials for Automotive Crashworthiness: A Review

8

1.1 Introduction

9

1.2 Materials

11

1.3 Thermoset and thermoplastic composites

12

1.4 Matrix

13

1.5 Test methodologies

14

1.5.1 Quasi-static test

14

1.5.2 Dynamic test

14

1.6 Crashworthiness design

15

1.7 Crashworthiness prerequisites

17

1.8 Energy-absorbing thermoset composite structures

18

1.9 Assessing factors of energy absorption capability

19

1.9.1 Crush force efficiency (CFE)

19

1.9.2 Stroke efficiency (SE)

20

1.9.3 Initial failure indictor (IFI)

20

1.9.4 Specific energy absorption ES

20

1.10 Volumetric Energy absorption capability

21

1.11 Energy absorption

21

1.12 Literature survey

22

1.13 Conclusions

30

Acknowledgments

31

References

31

2

40

Wood Flour Filled Thermoset Composites

40

2.1 Introduction

41

2.2 Wood polymer composites

43

2.3 Wood flour composites (WFCs)

44

2.3.1 Processing of WFCs

45

2.3.2 Properties of WFCs

46

2.3.2.1 Mechanical properties

46

2.3.2.2 Surface roughness and wettability

48

2.3.2.3 Water absorption tests

49

2.3.2.4 Thermo-gravimetric analysis (TGA)

50

2.3.2.5 Differential scanning calorimetry (DSC)

51

2.3.2.6 Dynamic mechanical tests (DMA)

52

2.3.2.7 Creep test

52

2.3.2.8 Flammability characteristics

54

2.3.2.9 Tomography

55

2.3.3 Scanning electron microscopy (SEM) analysis

56

2.4 Practical applications

58

Conclusions

59

References

59

3

73

Experimental and Analysis of Jute Fabric with Silk Fabric Reinforced Polymer Composites

73

3.1 Introduction

74

3.2 Materials and methods

75

3.3 Preparation of composites

76

3.4 Experimentation

77

3.5 Results and discussions on experimentation

79

3.6 Analysis

82

Conclusion

85

References

86

4

88

Biosourced Thermosets for Lignocellulosic Composites

88

4.1 Introduction

89

4.2 Urea, also a natural material for wood adhesives

90

4.3 Tannin thermoset binders for wood adhesives

92

4.4 New technologies for industrial tannin adhesives

95

4.5 Tannin-Hexamethylenetetramine (Hexamine) adhesives and adhesives with alternative aldehydes

97

4.6 Hardening by tannins autocondensation

100

4.7 Lignin adhesives

102

4.8 Protein adhesives

105

4.9 Carbohydrate adhesives

105

4.10 Unsaturated oil adhesives

107

Conclusions

111

References

111

5

119

Hybrid Bast Fibre Strengthened Thermoset Composites

119

5.1 Introduction

120

5.2 Bast fibre

121

5.2.1 Surface morphology and elemental composition analysis

121

5.2.2 Structural composition and the physical properties of the bast fibre

123

5.2.3 Composition and the properties of the different bast fibre

124

5.3 Advantage and limitation of bast fibre as reinforcing material

125

5.4 Surface modification of bast fibres

126

5.5 Methods for surface modification of natural fibres

126

5.3.1 Physical methods

127

5.5.2 Chemical methods

127

5.5.2.1 Alkali treatment

127

5.5.2.2 Graft copolymerization

128

5.5.2.3 Acetylation

128

5.5.2.4 Treatment with isocyanate

128

5.5.2.5 Other chemical treatments

129

Conclusions

129

References

129

6

135

Nano-Carbon/Polymer Composites for Electromagnetic Shielding, Structural Mechanical and Field Emission Applications

135

6.1 Introduction

136

6.2 Shielding parameters of GNCs/Polyurethane nanocomposites

137

6.2.2 Characterizations and measurements

138

6.2.3 Analysis of microwave parameters

145

6.2.4 E?cient microwave absorbing properties:

148

6.3 Nanocomposite approach for structural engineering

153

6.3.1 GNCs as effective nanofiller

154

6.3.2 Dispersibility investigations: homogeneous distribution vs agglomeration and interfacial adhesion of GNCs

155

6.3.3 Raman mapping of GNCs nanocomposites

156

6.3.4 Optical imaging

157

6.3.5 Mechanical properties of GNCs/nanocomposites

158

6.3.3 Fracture mechanisms using fractography

162

6.3.4 Thermal and physical properties

164

6.4 MWNTs/nylon composite nanofibers by electrospinning

166

6.4.1 Synthesis of composite

167

6.4.2 Characterizations

168

6.4.3 I–V characteristic of the nanofiber composite

172

6.5 Carbon nanotube composite: Dispersion routes and field emission parameters

173

6.5.1 Synthesis of thin multiwall carbon nanotube composite

174

6.5.2 Characterization

176

6.3.3 Field emission parameters for the t–MWCNT–composite

180

Summary

183

References

185

7

196

Conductive Thermoset Composites

196

7.1 Introduction

197

7.2 Historical background of thermoset polymers

198

7.3 Method of Composite processing

201

7.4 Different types of CTC

204

7.4.1 Epoxy Based CTC

204

7.4.2 Polyurethane based CTC

204

7.4.3 Polyester based CTC

205

7.4.4 Polybenzoxanines based CTC

205

7.5 Properties of CTC

206

7.5.1 Thermal properties

206

7.5.2 Mechanical properties

206

7.5.3 Electrical properties

207

7.6 Applications of conductive thermoset composites

207

7.6.1 Electromagnetic interference (EMI) shielding

209

7.6.2 Anti-corrosive coatings

210

7.6.3 Shape memory application

211

7.6.4 Other applications

211

7.7 Problems and solution associated with CTC

212

Conclusion

214

Acknowledgment

214

References

215

8

224

Waterborne Thermosetting Polyurethane Composites

224

8.1 Introduction

225

8.2 PUD thermosetting composites

226

8.2.1 Inorganic oxide based PUD thermosetting composites

226

8.2.1.1 Silica-based PUD thermosetting composites

226

8.2.1.2 Titania (TiO2) based PUD thermosetting composites

231

8.2.1.3 Zinc oxide (ZnO) based PUD thermosetting composites

233

8.2.1.4 Other inorganic oxide-based PUD thermosetting composites

234

8.2.2 PUD thermosetting composites with metal (Ag and Au) nanoparticles

236

8.2.3 PUD/clay thermosetting composites

240

8.2.4 PUD/Carbohydrate thermosetting composites

242

8.2.4.1 Cellulose-based PUD thermosetting composites

242

8.2.4.2 Starch reinforced PUD thermosetting composites

245

8.2.5 PUD thermosetting composites reinforced with nanocarbon materials

247

8.2.5.1 Graphene oxide (GO), and reduced graphene oxide (rGO) based PUD thermosetting composites

248

8.2.5.2 Carbon nanotubes (CNTs) reinforced PUD thermosetting composites

249

Summary

250

Abbreviations

250

References

251

9

267

Classical Thermoset Epoxy Composites for Structural Purposes: Designing, Preparation, Properties and Applications

267

9.1 Introduction

269

9.2 Methods for modifying liquid epoxy compositions

271

9.2.1 Chemical modification of liquid epoxy compositions

272

9.2.2 Physico-chemical modification of liquid epoxy compositions

272

9.2.3 Methods of physical modification of liquid epoxy compositions

273

9.3 Physico-chemical aspects of the modification of epoxy polymers by dispersed and continuous fibrous fillers

275

9.3.1 Features of the formation of clusters in a polymer composite

275

9.3.2 Analysis of the surface interaction of fillers with epoxy oligomers

277

9.3.2.1 Surface interaction of inorganic fillers with epoxy oligomers

277

9.3.2.2 Surface interaction of organic fillers with epoxy oligomers

278

9.3.2.3 The mechanism of molecular interaction between epoxy polymer and filler

279

9.4 Effect of ultrasonic treatment regimes on the properties of epoxy polymers

280

9.4.1 Technological and operational properties of epoxy polymers

280

9.4.2 Physico-mechanical and technological properties of sonificated epoxy matrices

283

9.5 Ultrasonic intensification of prepregs formation

284

9.5.1 Process of capillary impregnation

284

9.5.2 Effect of ultrasonic modification regimes on the kinetics of impregnation of continuous fibrous fillers

285

9.6 Ultrasonic processing devices for liquid polymer systems

287

9.7 Modeling of the structure of oriented and woven fibrous materials

290

9.7.1 Physical models of a capillary-porous medium based on oriented fibrous fillers

291

9.8 Modeling of technical means for production of polymer composite materials

293

9.8.1 The technology of ultrasonic production of long-length epoxy composites

293

9.8.2 Modeling of technical means for thermoplastic production

295

9.9 Other applications of ultrasonic in the production of thermosets and thermoplastic

296

9.9.1 The effectiveness of ultrasonic treatment for the production of epoxy nanocomposites

296

9.9.2 Pepair technologies for the maintenance and restoration of polyethylene pipelines

297

Conclusions

299

References

300

10

307

A Review on Tribological Performance of Polymeric Composites Based on Natural Fibres

307

10.1 Introduction

308

10.2 Natural fibres

309

10.3 Polymer

310

10.4 Composite

313

10.5 Tribology

314

10.6 Friction and wear

317

Summary

332

Future Developments

336

References

337

back-matter

348

Keyword Index

348

About the Editors

349