Organic Pollutants in Wastewater I - Methods of Analysis, Removal and Treatment

von: Inamuddin

Materials Research Forum LLC, 2018

ISBN: 9781945291630 , 362 Seiten

Format: PDF

Kopierschutz: Wasserzeichen

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Preis: 135,00 EUR

Mehr zum Inhalt

Organic Pollutants in Wastewater I - Methods of Analysis, Removal and Treatment


 

frontpages

2

Table of Contents

6

1. Introduction

10

2. Features of magnetic solid phase extraction (MSPE)

11

2.1 Magnetic sorbent materials

12

2.2 Synthesis and characterization of magnetic sorbents

15

3. Overview of magnetically responsive bio-sorbents

19

3.1 Mechanism of magnetic biomaterial modifications

20

3.1.1 Magnetic fluid modification

20

3.1.2 Microwave aided magnetic modification

21

3.1.3 Mechano-chemical magnetic modification

22

4. Application of magnetically responsive bio-sorbents

23

4.1 Magnetically responsive biopolymer

25

4.2 Magnetically responsive plant derivatives

26

4.3 Magnetically responsive microalgae

27

4.4 Magnetically responsive activated carbons

32

4.5 Magnetically responsive microbial cells

34

5. Conclusions and future outlook

37

References

38

2

50

1. Introduction

51

2. Material and methods

52

2.1 Chemical and reagents

52

2.2 Treatment process

52

2.3 Analytical procedures

53

2.4 Statistical analysis

53

3. Results and discussion

53

3.1 Effect of pH

53

3.2 Effect of contact time

57

3.3 Effect of Fe+2 dose

57

3.4 Effect of H2O2 concentration

60

3.5 Effect of initial dye concentration

60

3.6 Effect of temperature

60

3.7 Effect of UV radiation

64

4. Kinetic modeling

66

5. Degradation, water quality and cytotoxicity of effluents

68

6. Conclusions

71

References

71

3

75

1. Introduction

76

2. Materials and methods

77

2.1 X-Ray diffraction

78

2.2 X-Ray photoelectron spectroscopy

81

2.3 Transmission electron microscopy (TEM)

84

2.4 UV –Visible spectroscopy

85

2.5 Photocatalytic activity

86

4. Conclusions

91

Acknowledgement

91

References

91

4

96

1. Introduction

97

1.1. Use of raw biomass as biosorbents

99

1.2 Mechanism of biosorption

102

2. Physicochemically treated biomass and their adsorption characteristics

104

3. Use of charred biomass

107

3.1 Production of biochar

108

3.2 Characteristics of biochar for adsorption

111

4. Conclusion

118

References

118

5

131

1. Introduction to carbon quantum dots

132

2. Structure of carbon quantum dots

133

3. Synthesis of carbon quantum dots

133

3.1 Top-down approach

134

3.1.1 Electrochemical method

134

3.2 Bottom-up approach

134

3.2.1 Hydrothermal method

135

3.2.2 Microwave method

136

3.3 Synthetic methods

137

4. Properties of carbon quantum dots

139

4.1 Optical

139

4.2 Biologically compatible

139

5. Applications of carbon quantum dots

139

5.1 Chemical sensing

139

5.2 Photocatalysis

140

5.3 Bioimaging

141

5.4 Drug delivery

142

6. Degradation of organic pollutants using carbon quantum dot based composites

143

7. Conclusions

145

References

145

6

157

1. Introduction

158

2. Methods of determination of Phenols

160

2.1 Physical methods

161

2.1.1 Solvent extraction

161

2.1.2 Liquid-liquid extraction

161

2.1.3 Three Phase Liquid System

162

2.1.4 Pervaporation

164

2.1.5 Membrane filtration

164

2.1.5.1 Reverse osmosis separation methods

164

2.1.5.2 Ultrafiltration

165

2.1.5.3 Nanofiltration

165

2.1.6 Adsorption

166

2.1.7 Cloud point extraction method

167

2.2 Chemical methods

168

2.2.1 Advanced oxidation process

168

2.2.2 Air oxidation

168

2.2.3 Catalytic wet air oxidation of phenol

168

2.2.4 Photodecomposition

168

2.2.5 Coupled ultrasound and Fenton’s reagent

171

2.2.6 Three phase electrode system

171

2.3 Biological Methods

173

2.3.1 Enzymatic degradation

173

2.3.2 Microbial degradation

177

3. Conclusions

180

References

180

7

191

1. Introduction

192

1.1 Advanced oxidation processes (AOPs)

193

1.2 Principle of heterogeneous photocatalysis

193

1.3 Semiconductor photocatalysts for water splitting

194

1.4 Applications of semiconductor photocatalysts

196

1.5 Modified TiO2 photocatalysts

198

1.6 Application of modified TiO2 photocatalysts

199

1.6.1 Metal loaded TiO2

199

1.6.2 Non-metal loaded TiO2

200

1.6.3 Metal halide loaded TiO2

202

1.7 Bismuth-based photocatalysts:

203

1.7.1 BiOBr Semiconductors

203

1.7.2 Bi2S3 semiconductors

203

Conclusions

204

References

204

8

215

1. Introduction

216

2. Features of oxide semiconductors for photocatalysis

217

3. Zinc oxide nanomaterials as photocatalyst

219

4. Titanium oxide nanomaterials as photocatalyst

223

5. Iron oxide nanomaterials as photocatalyst

226

6. Cerium oxide nanomaterials as photocatalyst

229

7. Conclusions

231

References

232

9

247

1. Introduction

248

2. Photocatalytic ZnO/graphene composites

249

2.1 ZnO/graphene composites

250

2.2 ZnO/reduced graphene oxide composites

251

3. Photocatalytic ZnO/carbon nanotube based semiconductor composites

254

4. Photocatalytic ZnO-silica, alumina, zeolite and clay based composites

257

5. Photocatalytic ZnO-luminescent agent based composites

260

6. Photocatalytic ZnO-transition metals, rare earth metals, and non-metals based composites

263

6.1 Transition metals-doped ZnO composites

263

6.2 Rare earth metals-doped ZnO composites

265

6.3 Non-metals-doped ZnO composites

266

7. Conclusion

267

References

267

10

282

1. Introduction

283

2. Heterogeneous photocatalysis

284

2.1 Titanium dioxide as photocatalyst

285

2.2 Electronic structure of TiO2

285

2.3 Physical properties of TiO2

285

2.4 Mechanism of TiO2 assisted heterogeneous photocatalysis

287

2.5 Modification of TiO2 photocatalysts

289

2.6 Nanocomposites and their classification

290

3. TiO2 based nanocomposites for photocatalytic degradation of organic pollutants

290

3.1 Organic Polymer based TiO2 nanocomposites for degradation of organic pollutants

290

3.2 Inorganic Polymer based TiO2 nanocomposites for degradation of organic pollutants

292

3.3 Metal oxide-based TiO2 nanocomposites for degradation of organic pollutants

293

3.4 Noble metal/ carbon-based TiO2 nanocomposites for degradation of organic pollutants

295

Conclusions

295

References

296

11

303

1. Introduction

304

2. Industrial pollutants and their impact on water

305

3. Treatment technologies

308

4. Agro industrial wastewater

310

4.1 Olive mill wastewater

310

3.2 Palm oil mill wastewater

320

3.3 Dairy industry

325

3.4 Tomato-processing wastewater

331

3.5 Fish-processing wastewater

331

3.6 Distillery wastewater

333

3.7 Molasses spent wash

333

3.8 Winery wastewater

336

Conclusions

343

References

343

keyword index

360

about the editors

361